So, it seems obvious that Batman and Green Arrow would be the most frequent team-up of the B&B era! Let's take a look at these meetings....
Brave and the Bold #71 (April-May, 1967) has the first B&B teaming of these two heroes, in a story by Bob Haney (who started the team-ups in B&B #50), with art by George Papp (the co-creator of Green Arrow), all under a cover by Carmine Infantino (who was the artist who started Batman's "new look"...which included the yellow oval).
"The Wrath of the Thunderbird" was a pretty simple story of Batman and Green Arrow facing off against a crooked promoter and save an Indian tribe..
...a reflection of what the average team-up was like at the time, but boy was that to change!
The Times Are A Changin'
This led to Green Arrow getting paired with Green Lantern (and Neal Adams getting the art assignment there as well with writer Denny O'Neil, creating the very famous pairing and socially relevant comics...) .
But it all started here with "The Senator's Been Shot!" in a story that's been reprinted more than a few times as well!
...and the lot of them gathered to prevent a shipment of drugs from being dumped in Gotham and make sure Batman recovered from his wounds.
"The Warrior in the Wheel-Chair" has been reprinted in color, in the first volume of the Legends of the Dark Knight: Jim Aparo hardcover.
This story was by Bob Haney and Jim Aparo, and was the first time Jim Aparo got to draw Green Arrow on a B&B cover...but it wouldn't be his last.
"Double Your Money...And Die" also made it into the first volume of the Legends of the Dark Knight: Jim Aparo hardcover, and Green Arrow would face that mystery villain again in the pages of B&B!
Double Your Pleasure
These stories are also reprinted in color in the second volume of the Legends of the Dark Knight: Jim Aparo hardcover.
More Group Fun
True, it was just another story by Bob Haney and Jim Aparo, but along with Green Arrow, it featured the Metal Men (robots of Dr. Will Magnus that fought evil and exhibited the properties of the metals they were made of), as well as reoccurring Batman B&B foe and femme fatale Ruby Ryder - who was previously in B&B #95, 123 and 135, menacing Batman, Plastic Man and Metamorpho).
"Legacy of the Doomed" (along with all but Ruby's first appearance) all made it into the second volume of the Legends of the Dark Knight: Jim Aparo hardcover.
One Last Time
This time Batman and Green Arrow faced the Gargoyle over an enchanted arrow..."The Arrow of Eternity".
This story also ended up in the second volume of the Legends of the Dark Knight: Jim Aparo hardcover.
Meet the New Boss, Same as the Old Boss
This time around, Batman was helping Green Arrow by introducing a friend's escape artist act...
...an oddly friendly thing for the "grim and gritty" Batman to do. Still, it was something for this B&B team to do to while away the time...
...and, sadly, "Shackles of the Mind" has yet to be reprinted.
One Last Hurrah
"The Falcon's Lair" has not been reprinted, but at least the cover featured the newer Green Arrow logo...which had made it onto Green Arrow's first mini-series as well.
Batman and Green Arrow weren't done teaming up either, still working together in the Justice League, and even in more than a few issues of Detective Comics.
B&B seein' ya!